Plasma‐catalytic Ammonia Synthesis via Eley‐Rideal Reactions: a Kinetic Analysis

Synthesis of Phosphorus Derivatives via Multicomponent Reactions

Stable derivatives of oxaphosphaphenanthrenes were prepared using multicomponent reactions of 3-bromo-2-naphthol, dialkyl acetylenedicarboxylate and trimethyl or triphenyl phosphite under microwave conditions with good yields. 

synthesis of phosphorus derivatives via multicomponent reactions

A novel synthesis of diastereomerically pure spiro- oxindolopyrrolizidines and oxindolopyrrolidines via cycloaddition reactions of azomethine ylides

An efficient one-pot three-component procedure for the synthesis of new chiral spiro oxindolopyrrolidines/pyrrolizidines with highly regio- and diastereo-enantio, selective from 1,3-dipolar cycloaddition of azomethine ylides and chiral menthol-drived trans-cinnamic are described. The mechanism of the reaction is discussed on basis of the assignment of the absolute configuration of one of the cy...

Organocatalytic kinetic resolution via intramolecular aldol reactions: enantioselective synthesis of both enantiomers of chiral cyclohexenones.

Kinetic resolution of 6-aryl-2,6-hexanediones was achieved with chiral secondary amine catalyzed intramolecular aldolization. The current kinetic resolution protocol enables the synthesis of both enantiomers of cyclohexenones with moderate to good enantioselectivity.

Performance evaluation and availability analysis of ammonia synthesis unit in a fertilizer plant

This paper discusses the performance evaluation and availability analysis of ammonia synthesis unit of a fertilizer plant. The fertilizer plant is a complex and repairable engineering system comprises of various units viz. shell gasification and carbon recovery, desulphurization, co-shift conversion, decarbonation, nitrogen wash and ammonia synthesis etc. One of the most important functionaries...